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Thermodynamics

Quiz Number:  6
Course Name:  Chemistry
Course No.132
Quiz N0. : 6
Teacher:  Billy Cook
Teacher's Home Page:  http://www.iaonline.com/chemistry/chemistr1.htm
Teacher's Email:  Bcook@icc.cc.il.us

No. of Questions= 5


1.  Which of the following must have a negative value for an exothermic reaction?
a) enthalpy change
b) entropy change
c) free energy change
d) electrode cell potential
e) equilibrium constant
2.  Which of the following is true when one mole of dry ice sublimes to gas at -78oC?

 

        1. The entropy decreases.

        2. The entropy increases.

        3. The order increases.

a) 1 only
b) 2 only
c) 3 only
d) 1 and 3 only
e) 2 and 3 only
3.  The heat of vaporization of methanol, CH3OH, is 36.8 kJ/mol. Its boiling point is 64.7oC. The change in entropy for the vaporization of methanol in J/mol.K   is:
a) -17.8
b) 3.41
c) 17.8
d) 109
e) 569
4.  Which of the following processes involve an increase in DSo?

1.      Br2(l) aro.jpg (800 bytes) Br2(g)

2.     2 NO(g)  +  O2(g) aro.jpg (800 bytes)  2 NO2(g)

3.     MgSO3(s) aro.jpg (800 bytes)  MgO(s)  +  SO2(g)

4.     2 HgO(s) aro.jpg (800 bytes) 2 Hg(l)   +  O2(g)

a) 1 and 2
b) 2 and 3
c) 3 and 4
d) 1, 3, and 4
e) 1, 2, 3, and 4
5.  Calculate DSo  for the decompostion of ozone, O3, to oxygen.

2 O3(g) aro.jpg (800 bytes) 3  O2(g)

So = 205 J/mol.K for O2(g)  and 239 J/mol.K  for O3(g) at 25oC.

a) +137 J/mol.K
b) -137 J/mol.K
c) +34 J/mol.K
d) -34 J/mol.K
e) +444 J/mol.K





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